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The production of potassium alum from alunite is archaeologically attested on the island Lesbos. This site was abandoned in the 7th century but dates back at least to the 2nd century CE. Native alumen from the island of Melos appears to have been a mixture mainly of alunogen (Al 2 (SO 4) 3 䞍H 2 O) with potassium alum and other minor sulfates.

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Alunite is a hydroxylated aluminium potassium sulfate mineral, formula K Al 3 (S O 4) 2 (OH) 6 was first observed in the 15th century at Tolfa, near Rome, where it is mined for the manufacture of alum.First called aluminilite by J.C. Delamétherie in 1797, this name was contracted by François Beudant three decades later to alunite.

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Also known as Angel Wing, Alunite is often found in a combination of colors, usually in pairing with red.. The stone may be red with white streaks all over, or contain a pairing of red with light, creamy pink or yellow blotches of color spread across the stone in varying amounts, depending on the minerals.

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